In this article, I examine how Syrian refugee men and women shifted their household divisions of labor in their initial years of resettlement in the United States. I combine and extend relational approaches from gender theory and economic sociology to examine how men’s and women’s behaviors shifted, the resources engendered by behavioral shifts, and how they interpreted and compensated for new behaviors and resources. I show that shifts in Syrian household divisions of labor occurred at the intersection of inequalities in social policies, labor markets, and households. As a result of limited social assistance, the refugee families needed to earn an income within months of their arrival. The Syrian men entered the labor market, in keeping with a breadwinning expectation for their labor, but could only access menial jobs that limited their time and opportunity to learn English. Women, meanwhile, did not enter the labor market full-time and could attend English classes. By observing this divergence in men’s and women’s language learning, I theorize human capital as a gendered outcome of household divisions of labor.